The Unique Crystallization Behavior of Buffalo Milk Fat
نویسندگان
چکیده
A full comprehension of milk fat crystallization is important for the structural development dairy products such as butter, ice cream, and cheese. The influence triacylglycerol (TAG) composition on dynamic nanostructure formed crystals was investigated using two chemically different types fat, namely buffalo cow fats (BMF; CMF). TAG determined liquid chromatography mass spectrophotometry (LCMS), whereas differential scanning calorimetry (DSC), small- wide-angle X-ray scattering (SAXS WAXS), polarized light microscopy (PLM) were used to characterize behavior fats. total 37 species identified in both BMF CMF, but proportions. In particular, found have a higher amount low-molecular-weight TAGs comparison CMF. This difference chemical explains kinetics polymorphic transformation samples. Specifically, it clarifies delay nucleation β′-polymorph also showed rate due its proportion saturated melting range. Finally, this work presents novel interpretation mechanism formation β-polymorph (53 Å), which has recently become subject vivid debate studies.
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ژورنال
عنوان ژورنال: Crystal Growth & Design
سال: 2021
ISSN: ['1528-7483', '1528-7505']
DOI: https://doi.org/10.1021/acs.cgd.0c01543